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Here are the key points;
https://www.progreen.co.uk/weed-control/total/roundup-proactive-360
https://www.progreen.co.uk/weed-control/total/roundup-provantage-480
Mainly relates to a cleaner products, with newer surfactants, 'cling-ability' and rain fastness.
Key is; Safe to the operator, public and pets - non hazardous as classified by COSHH
Also, if you search LJN you'll find some detailed discussions on the newer products from Monsanto, along with views regarding the older, cheaper Gylpho formualtions.....
Re: mixing, you'll need to read product labels of each item but for paradise is states: Can be used in a tank-mix with glyphosate or diluted with water on its own
Proshield or Pistol will do similar as a single product, but watch application on hard surfaces.