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Adam, see my reply to Dylan under the heading Indian stone cleaner
https://landscapejuicenetwork.com/forum/topics/indian-sandstone-pat...
Sodium hypochlorite is the go-to chemical for black spot. It's a bleach so it's not ideal to get on plants, but then again neither is acetic acid which is marketed as an "organic" cleaner.
Thank you guys, much appreciated advice!