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Depends on the wood. If it's oak or pine it'll be soaked in creosate as well as diesel and oil. But if you can find some Jarrah or Azobe (there are also a few other tree species used for sleepers that dont need treating but I can't remember any) sleepers these will only be covered in diesel and oil so you be able to power wash them clean.
Possibly newer sleepers would be okay if they're pine or oak as they dont use creosote anymore but you'd have to check if this is safe for use in water courses.
Maybe a question to put to the Environment Agency, getting it wrong could prove very costly.
I used Jarrah sleepers for a walkway through a bog along time ago, on a National Trust for Scotland property, there unbelievably hard and great for a job like that. Not sure how easy they are to get now, their sought after by craftman who plank them for furniture making