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Do you have pictures?
Thanks.Sorry, no pictures; only saw them when customer pointed them out. Will try lemon (or possibly vinegar?). Just wasn't sure of the effect of acid on porcelain. If we go this way I will try it on an off-cut or somewhere out of the way just in case.
Fresh lemon juice, from lemons! - not from jar, and brush in for 5 mins. Rinse off lots of water and repeat as required. Do on a test area out of way first to check re damage.
http://www.pavingexpert.com/home.htm ; is an excellent site with all the paving questions/problems. There a whole section dedicated to removing stains including rust.